Synthesis and Spectroscopic Studies of Some Metal Complexes of [3-(3-(2-chloroacetyl)thioureido)pyrazine-2-carboxylic acid]
Keywords:
: 3-Amino pyrazine-2-carboxelic acid, chloroacetyl isothiocyanate, complexes
Abstract
A new ligand [3(3(2chloroacetyl) thioureido)pyrazine-2-carboxyliIcacid](CPC)was synthesized by reaction of rized by imicro elmental analysis C.H.N.S.,FT-IR,UV-Vis and 1H-13CNMR spectra, some transition metals complex ofIthis ligand were Prepared and characterized byiFT-IR,UV-Vis spectra conductivity measurements magnetic susceptibility and atomic absorption. From the obtained results the molecular formula of all prepared complexes were[M(CPC)2](M+2i=Mn. Co, Ni, Cu, Zn, Cd and Hg),the proposedi geometrical structure for all complexes were as tetrahedral geometry except copper complex has square planer geometry.Downloads
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References
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3- Baldwin. MV, Sonia DA, Sindhu,TJ, MeenaC, Bhat,AR, Krishnakumar K.World J PharmPharmSci2013;3: 1124–1132.
4-Endredi H,Billes F,andHolly S; (2003)J.Mol; Struct. Theochem., 633,739(2003)
5-Ding,B.Yankg,E. Guo,j.andWang,X.; (2008)Inorg.Chem.Commun.,11,509
6-Tanase,s.VanSon,M.Gerard,A.Gelder,R
.Bouwman,EandReedijk,J.. (2008);Polyhedron,15,2967
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8-Ptasiewicz-BACK,J andLeciejewicz,J(1997).;Polish.J.Chem.,71,1350
9-Sahar,Issam,M.EL-Asmy, H.andMohamamed, E.; (2009). “Complexes of 3-amino pyrazine- 2- carboxelic acide,withVO2+,Pd(II), W(VI)andUO22+and Preparationand characterizationâ€.ICAIJ,4(1)[31-35]
10-.Kabbani, A.T; Ramadan, H.; Hammuud, H.H. and Hanuom, A.M.G.; (2005) “Synthesis of some metal complexes of N-[(benzoyl amino)-thioxomethyl] amino acid (HL)â€; Journalof the Universityof Chemical Technology and Metallurgy,40(4): 339-344.
11-Silverstein,R.M.;Bassler, G.C. and Morrill, T.C;(1981) “Spectroscopicidentification of organic compoundsâ€, 4th Ed., John Wiley and Sons, New York.
12-Marah,J.;(1991) “AdvancedOrganic Chemistryâ€; 4th Ed., J. Wiley and Sons, New York
13-Cary, F.A.(2005) “Organic Chemistryâ€, 6th Ed. the M.C Graw-Hill companies, Inc.,New York.
14-Seenaiah D., Venkatesh B.C., Padmaja A.and Padmavathi V. (2013)“Synthesis of some new oxazolinyl/thiazolinyl/imidazolinyl- benzoxazoles,benzothiazoleisand benzimidazoles†;Indian Journal of Chemistry , 52B : 942-948.
15-Kumar, K.; Satyanarayana, P.and Reddy, B.;(2013)“NaHSO4-SiO2-Promoted Solvent-FreeSynthesisiofiBenzoxazoles,Benzimidazoles, and Benzothiazole Derivatives†;Journal of Chemistry , 1 : 1-10.
16-Diebbar-Sid, S., Benali-Baitich, O. and Deloume,J.P.; (2001) “Synthetic and Structural Studies of Some Bivalent Transition Metal Complexes with Oxygen and Nitrogen Containing Schiff Base†;J. mol. Struct., 569: 121.
17-Nakamoto K; (1996). ((Infrared spectra of inorganic and coordination compounds )) 4th ed , John wily and Sons , New York ,
18- Sadiaa M .Al- Hashimi , sarhan B .M. and salm an A.w,; (2002) ((Synthesis and characterization of N-acetyl –Dl –tryptophan with some metal ions)); Iraq J .chem ;28,1-11.
19-Abdul sattar Z.k; M.Sc. (2013) Thesis university of Al-anbar,.
20.Mulay,L.,(1977)“Magnetic Susceptibilityâ€,John wiley and sons;New York;part1,vol(4).
21-Sarhan, B .M.; Abed, A.H. and Rumez, R.M. (2013) “Synthesis and characterization of some mixed ligand complexes of quinaldic
acid andα -picoline with some metal saltsâ€;AL-Mustansiriyah Journal of science,24(4): 65-74.
22-Lever A.B.P,; (1968) ((Inorganic electronic spectroscopy)) Elsevier publishing company Amsterdam, London, New York.
23-Mukhlis .A.J; Sarhan.B.M, and Rumer.R.M; ((Synthesis and characterization of some new metal complexes of (5-c-dimethyl malonyl-pentulose-Æ”-lactone-2,3-endibenzoate)); Ibn-Al-Haitham J. for pur and Apl.Sci; 25,(2) ,316-327 (2012) .
24-Sarhan.B.M; A waad .M.A.and Hammed.W.k;(2012).,((Synthesis and characterization of complexes of [N-tris(hydroxyl methyl) methyl-2-amino ethane sulphonic acid])); J. of college of Education;5, 468-481
25-Huheey,J.E(1983)((lnorganicchemistr,
principles of Structure and Reactivity)) 3thed ,Harper lnternational SI Edition;Maryland
Published
2018-01-10
How to Cite
M . Sarhan, B. (2018). Synthesis and Spectroscopic Studies of Some Metal Complexes of [3-(3-(2-chloroacetyl)thioureido)pyrazine-2-carboxylic acid]. Al-Qadisiyah Journal of Pure Science, 22(2), 10-19. Retrieved from https://journalsc.qu.edu.iq/index.php/JOPS/article/view/567
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